The Tallahassee-St. Marks Trail is a great place for walking, rollerblading, or biking. It is paved at kept up very nicely. You don't have to be concerned about traffic because there are no motor vehicles allowed on the trail, and places where roads cross the trail are very well marked. There is an unpaved horse trail that runs along side of the trail as well.
The trail runs the whole way from Tallahassee to Saint Marks. There are lots of places along Woodville Highway where you can park your car and jump onto the trail since it is over 16 miles long!
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